Query 3

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course PHY-242

query problem 15 introductory problem sets temperature and volume information find final temperature.

When temperatureand volume remain constant what ratio remains constant?

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Your Solution:

Charles law apply such that we can set up

V1 / T1 = V2 / T2

confidence rating #$&*:

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Given Solution:

** PV = n R T so n R / P = V / T

Since T and V remain constant, V / T remains constant.

· Therefore n R / P remain constant.

· Since R is constant it follows that n / P remains constant. **

STUDENT QUESTION:

I don’t understand why P is in the denominator when nR was moved to the left side of the equation

INSTRUCTOR RESPONSE:

The given equation was obtained by dividing both sides by P and by T, then reversing the sides.

We could equally well have divided both sides by v and by n R to obtain

P / (n R) = T / V,

and would have concluded that P / n is constant.

To say that P / n is constant is equivalent to saying the n / P is constant.

Your Self-Critique:

I think your question was not specific enough since I answered a correct answer, but your answer differed from my answer.

Your Self-Critique Rating: 3

@&

Your answer says that the ratio V / T remains constant.

However this is just a restatement of the condition of the problem, and does not constitute an answer to the question.

*@

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Question: why, in terms of the ideal gas law, is T / V constant when only temperature and volume change?

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Your Solution:

PV = nRT

nRT = PV

T = PV/(nR)

T/V = P/(nR)

T / V can also be constant when the variables below change:

P is pressure, n is number of moles and R is universal gas constant.

confidence rating #$&*:

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Given Solution:

** STUDENT ANSWER AND INSTRUCTOR RESPONSE:

They are inversely proportional. They must change together to maintain that proportion.

INSTRUCTOR RESPONSE:

You haven't justified your answer in terms of the ideal gas law:

PV = n R T so V / T = n R / P.

If only T and V change, n and P don't change so n R / P is constant.

Therefore V / T is constant, and so therefore is T / V.

You need to be able to justify any of the less general relationships (Boyle's Law, Charles' Law, etc.) in terms of the general gas law, using a similar strategy. **

Your Self-Critique:

ok

Your Self-Critique Rating: ok

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Question: prin phy Ch 13.26. Kelvin temperatures corresponding to 86 C, 78 F, -100 C, 5500 C and -459 F.

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Your Solution:

Per your instruction, I am skipping this problem

confidence rating #$&*: ok

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Given Solution:

The Kelvin temperature is 273 K higher than the Celsius temperature (actually 273.15 below, but the degree of precision in the given temperatures is not sufficient to merit consideration of tenths or hundredths of a degree).

· 86 C, -100 C and 5500 C are therefore equivalent to ( 86 + 273 ) K = 359 K, -100 + 273 K = 173 K, (5500 + 273) K = 5773 K.

The freezing point of water is 0 C or 32 F, and a Fahrenheit degree is 5/9 the size of a Celsius degree. Therefore

· 78 F is (78 F - 32 F) = 46 F above the freezing point of water.

· 46 Fahrenheit degrees is the same as (5/9 C / F ) * 46 F = 26 C above freezing.

· Since freezing is at 0 C, this means that the temperature is 26 C.

· The Kelvin temperature is therefore (26 + 273) K = 299 K.

Similar reasoning can be used to convert -459 F to Celsius

· -459 F is (459 + 32) F = 491 F below freezing, or (5/9 C / F) * (-491 F) = 273 C below freezing.

· This is -273 C or (-273 + 273) K = 0 K.

· This is absolute zero, to the nearest degree.

Your Self-Critique:

ok

Your Self-Critique Rating: ok

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Question: prin phy and gen phy Ch 13.30 air at 20 C is compressed to 1/9 of its original volume. Estimate the temperature of the compressed air assuming the pressure reaches 40 atm.

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Your Solution:

per your instruction, I am skipping this question

confidence rating #$&*: ok

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Given Solution:

First we reason this out intuitively:

If the air was compressed to 1/9 its original volume and the temperature didn’t change, it would end up with 9 times its original pressure.

However the pressure changes from 1 atm to 40 atm, which is a 40-fold increase.

The only way the pressure could end up at 40 times the original pressure, as opposed to 9 times the original, would be to heat up. Its absolute temperature would therefore have to rise by a factor of 40 / 9.

Its original temperature was 20 C = 293 K, so the final temperature would be 293 K * 40/9, or over 1300 K.

Now we reason in terms of the ideal gas law.

P V = n R T.

In this situation the number of moles n of the gas remains constant. Thus P V / T = n R, which is constant, and thus P1 V1 / T1 = P2 V2 /T2.

The final temperature T2is therefore

· T2 = (P2 / P1) * (V2 / V1) * T1.

From the given information P2 / P1 = 40 and V2 / V1 = 1/9 so

· T2 = 40 * 1/9 * T1.

The original temperature is 20 C = 293 K so that T1 = 293 K, and we get

· T2 = 40 * 1/9 * 293 K,

the same result as before.

Your Self-Critique:

ok

Your Self-Critique Rating: ok

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Question: query gen phy ch 13.38 fraction of air released after tire temp increases from 15 to 38 C at 220 kPa gauge

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Your Solution:

per your instruction, I am skipping this question

confidence rating #$&*: ok

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Given Solution:

(Note that the given 220 kPa initial gauge pressure implies an absolute pressure of 311 k Pa; assuming atmospheric pressure of about 101 k Pa, we add this to the gauge pressure to get absolute pressure).

Remember that the gas laws are stated in terms of absolute temperature and pressure.

The gas goes through three states. The temperature and pressure change between the first and second states, leaving the volume and the number n of moles constant. Between the second and thirdstates pressure returns to its original value while volume remains constant and the number n of moles decreases.

From the first state to the second:

T1 = 288 K, T2 = 311 K so T2 / T1 = 311 / 288 = 1.08, approx.

This is approx. an 8% increase in temperature. The pressure must therefore rise to

P2 = 3ll / 288 * 321 kPa = 346 kPa, approx

(note that we have to use actual rather than gauge pressure so init pressure is 220 kPa + 101 kPa = 321 kPa, approx. )

From the second state to the third, pressure is then released by releasing some gas, changing the number n of moles of gas in order to get pressure back to 331 kPa. Thus

n3 / n2 = P3 / P2 = 321 kPa / 346 kPa or approximately .93, which would be about a 7% decrease. So we have to release about 7% of the air.

Note that these calculations have been done mentally, and they might not be particularly accurate. Work out the process to botain the accurate numerical results.

Note also that temperature changes from the second to third state were not mentioned in the problem. We would in fact expect a temperature change to accompany the release of the air, but this applies only to the air that escapes. The air left in the tire would probably change temperature for one reason or another, but it wouldn't do so as a direct result of releasing the air.

STUDENT QUESTION

It seems that the air goes from 288 to 311 K, so the ratio should be n2 / n1 = 288 / 311 and the proportional loss should be about (1 - 288 / 311)

INSTRUCTOR RESPONSE

The Kelvin temperature goes from 288 K to 311 K.

If the air is released at constant pressure, then volume and pressure remain constant while temperature and number of moles vary according to

n T = P V / R

so that

n1 T1 = n2 T2, and

n2 = n1 * (T1 / T2) = n1 * (288 / 311)

and the change in amount of gas is n1 - n2 = n1 - 288/311 n1 = n1( 1 - 288 / 311), or about 7.4% of n1.

If the temperature is first raised to 311 K, then the gas is released, it is the pressure and amount of gas that change. In that case the change in the amount of the gas is n1 - n3 = n1 - (321 kPa / 346 kPa) * n1 = n1 ( 1 - 321 / 346), or about 7.2% of n1.

The fractions 288/311 and 321 / 346 don't differ by much, not do the percents, but they do differ.

Your Self-Critique:

ok

Your Self-Critique Rating: ok

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Question: `q001. The temperature of a certain object increases from 50 Celsius to 150 Celsius. What is its change in temperature in Celsius?

Convert 50 Celsius and 150 Celsius to Kelvin.

What is the change in temperature in Kelvin?

What is the change in temperature in Fahrenheit?

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Your Solution:

Change in temperature = 150 C - 50 C = 100 C

To Kelvin --> 50 C + 273 = 323 K

To Kelvin --> 150 C + 273 = 423 K

The change in temperature in Kelvin is:

423 K - 323 K = 100 K

The change in temperature in Fahrenheit is:

302 F - 122 F = 180 F

confidence rating #$&*:

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Self-Critique Rating: 3

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Question: `q002. A sample of gas originally at 0 Celsius and pressure 1 atmosphere is compressed from volume 450 milliliters to volume 50 milliliters, in which state its pressure is 16 atmospheres. What is its temperature in the new state?

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Your Solution:

(P1 * V1)/T1 = (P2 * V2)/T2

(P1 * V1) * T2 = (P2 * V2) * T1

(1 atm * 450 ml) * T2 = (16 atm * 50 ml) * 273 K

( 450 ml * atm) * T2 = 218,400 atm * ml * K

T2 = 485.333 K = 212.333 C

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Self-Critique Rating:

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Question: `q003. What product or ratio involving P, V, n and T would remain constant if V and T were held constant?

Why does this make sense?

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Your Solution:

PV = nRT

nRT = PV

T = PV/(nR)

T/V = P/(nR)

If T and V can be indirectly held constant, then P, n, R, can be held constant. P directly, n indirectly and R indirectly

confidence rating #$&*:

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Self-Critique Rating: OK

@&

Your reasoning shows that P / n remains constant.

Of course P / (n R) also remains constant, but since R is always constant this statement contains no more information than just the statement that P / n remains constant.

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Question:

Openstax:

Large helium-filled balloons are used to lift scientific equipment to high altitudes. (a) What is the pressure inside such a balloon if it starts out at sea level with a temperature of 10.0ºC and rises to an altitude where its volume is twenty times the original volume and its temperature is - 50.0ºC ? (b) What is the gauge pressure?

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Your solution:

a)

Initial: temp 283 K, pres 1 atm, vol 1 cm^3

Final: temp 223 K, pres x atm, vol 20 cm^3

(P1 * V1)/T1 = (P2 * V2)/T2

(P1 * V1) * T2 = (P2 * V2) * T1

(1 atm * 1 cm^3) * 223 K = (x atm * 20 cm^3) * 283 K

223 atm * cm^3 * K = x atm * 5660 cm^3 * K

223/5660 atm = x

b)

3992 k Pa - 101 k Pa = 3891 k Pa

@&

Your 3992 kPa doesn't seem to be connected to anything in the preceding. It just suddenly appears with no justification. So it's hard to tell what your reasoning is here.

You have determined that the pressure is 223 / 5660 atm, and that looks good.

*@

confidence rating #$&*: 3

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Given Solution:

Simple reasoning: the volume increases by a factor of 20, which by itself would imply that the pressure decreases by a factor of 20.

But absolute temperature also decreases by a factor of 223 / 283, which would also imply a pressure decrease.

Bottom line: The pressure changes by factor (1/20) * (223/283) = .039, ending up at .039 of its original value.

More reliable analysis:

If V_0 and V_f are the initial and final volumes, then

V_f / V_0 = 20

The initial and final temperatures are 10 C = 283 K and -50 C = 223 K, so the ratio of temperatures is

T_f / T_0 = 223 / 283.

Since no helium escapes, n is constant to the PV = n R T implies that P V / T is constant. Thus

P_0 V_0 / T_0 = P_f V_f / T_f.

Solving this for the pressure P_f we obtain

P_f = P_0 * V_0 / V_f * T_f / T_0 = P_0 * (1/20) * (223/283) = P_0 * .039.

That is, the pressure at the new altitude is about .039 that at the surface.

Assuming the surface pressure to have been 1 atmosphere, the gauge pressure at altitude would be (.039 atm - 1 atm) = -.961 atm.

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Self-critique (if necessary):

You are using different atm units from me, so I can’t fully check my answer for part b.

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Self-critique Rating: 3

@&

You have determined that the pressure is 223 / 5660 atm, which is about .039 atm. This agrees completely with the given solution.

However that 3992 kPa doesn't seem connected to anything.

The bottom line is that a pressure of .039 atm is .961 atm lower than atmospheric pressure, so the gauge pressure is -.961 atm.

If you substitute 101.3 kPa for atm you will get the gauge pressure in kPa.

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Question:

(a) What is the average kinetic energy in joules of hydrogen atoms on the 5500ºC surface of the Sun?

(b) What is the average kinetic energy of helium atoms in a region of the solar corona where the temperature is 6.00×10^5 K ?

The average kinetic energy of particles at temperature T is

KE_ave = 3/2 k T,

where k = R / N_A is the Boltzmann constant (R is the gas constant and N_A is avagodro's number).

The average kinetic energy of a particle does not depend on what kind of particle it is. However the less massive the particle, the greater will be its speed at the average kinetic energy.

At 5500 C the absolute temperature is 5773 K so the average KE of a particle is

KE_ave = 3/2 k T = 3/2 * 1.38 * 10^-23 Joules / (particle Kelvin) * 5773 K = 1.19 * 10^-19 Joules.

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Your solution:

a)

Converting from C to Kelvin

5500 C + 273 = 5723 Kelvin

Maxwell's distribution:

v = sqrt(3kT/m)

When temperature T is 5723 K, Boltzmann's constant k is 1.38 * 10^-23 J/K and mass m of hydrogen atom is 1.67372 x 10^-24 g.

Therefore,

v = sqrt(3 * 1.38 * 10^-23 * 5723/1.67372 * 10^-24)

v = 141560.23 m/s

kinetic energy is

E = 0.5mv²

E = 0.5 * 1.67372 g * 10^-24 * (141560.23 m/s)²

E = 1.677 * 10^-14 J

b)

Maxwell's distribution:

v = sqrt(3kT/m)

When temperature T is 600,000 K, Boltzmann's constant k is 1.38 * 10^-23 J/K and mass m of helium atom is 6.64648 x 10^-24 g.

Therefore,

v = sqrt(3 * 1.38 * 10^-23 * 600,000/6.64648 * 10^-24 g)

v = 3737316.5946 m/s

kinetic energy is

E = 0.5mv²

E = 0.5 * 6.64648 g * 10^-24 * (3737316.5946 m/s)²

E = 4.64 x 10^-11 J

confidence rating #$&*: 3

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Given Solution:

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Self-critique (if necessary): N\A

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Self-critique Rating: N/A

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Question: query univ phy 17.112/ 17.114 / 17.116 (15.106 10th edition) 1.5 * 10^11 m, 1.5 kW/m^2, sun rad 6.96 * 10^8 m.

How did you calculate the total radiation of the Sun and how did you use this result to get the radiation per unit area?

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Your Solution:

H is the power density at the sun's surface (in W/m2)

R is the radius of the sun

D is the distance from the sun

Radiation = H * R^2/D^2

= 1500 W/m^2 * (6.96 * 10^8 m)^2 / (1.5 * 10^11 m)^2

= 1.634904 * 10^43 W/m^2

By using Radiation = H * R^2/D^2 formula, I was able to get the radiation per unit area answer.

confidence rating #$&*: 3

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Given Solution:

Outline of solution strategy:

If we multiply the number of watts per unit of area by the surface area of the Sun we get the number of watts radiated from the Sun.

The energy flows outward in a spherically symmetric manner; at any distance the entire power is distributed over the radius of a sphere concentric with the Sun and of radius equal to the distance.

So if we divide that number of watts by the area of a sphere whose radius is equal to that of the Earth’s orbit, we get the number of watts per unit of area at that distance.

This strategy is followed in the student solution given below:

Good student solution:

Surface area of sphere of radius r is 4 pi r^2; if flux intensity is I then flux = 4 pi r^2 I.

When r = 1.5 * 10^11 m, I = 1500 W / m^2, so the flux is 4 pi r^2 I = 4 pi * (1.5 * 10^11 m)^2 * 1500 W / m^2 = 4.28 * 10^26 watts.

4.28055 x 10 ^ 26 W / (4*`pi * (6.96 x 10 ^ 8 m)^2) = 4.28055 x 10 ^ 26 W / 6.08735 x 10 ^ 18 m^2 = 70318775.82 J/s/m^2 = 7.03 x 10 ^ 7 J/s/m^2

If the sun is radiating as an ideal blackbody, e = 1, then T would be found as follows:

H = `dQ/`dt = 4.28055 x 10 ^ 26 W = (4*`pi * (6.96 x 10 ^ 8 m)^2) * (1) * (5.67051 x 10^-8 W/m^2*K) * T^4

So T^ 4 = 4.28055 x 10 ^ 26 W / 6.087351 x 10 ^ 18 m^2) * 1 * (5.67051 x 10^-8 W/m^2*K)

T^4 = 1.240 * 10 ^ 15 K ^4

T = 5934.10766 K on surface of sun. **

Your Self-Critique:

When I am asked to find the total radiation, I expected to see an answer in W/m^2. The answer which you provided gave a temperature in Kelvin, when the question asked for radiation. Is radiation measured in degrees Kelvin?

I used this source to calculate my answer:

http://www.pveducation.org/pvcdrom/properties-of-sunlight/solar-radiation-in-space

@&

@&

The 1500 kW / m^2 is at the Earth, not the Sun.

This problem needs to be reasoned out based on geometry, not a meaningless (but possibly correct) canned formula someone posted on a website.

The formula would give the radiation intensity at the Earth due to the radiation from the Sun.

The results of this calculation have nowhere near the 10^43 magnitude you report. More like 10^-2.

If you plug in the 7.03 * 10^7 J/s/m^2 of the given solution for H you should get the 1500 W / m^2 at the surface of the Earth.

However an acceptable solution of the problem involves the geometry of spheres and possibly proportionalities.

*@

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Your Self-Critique Rating: 2

@&

The given solution continues with the calculation of the temperature at the surface of the Sun.

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Question: univ phy (omitted from 12th edition, but should be worked now) was 17.115 Solar radiation of intensity 600 watts / m^2 is incident on an ice sheet. The temperature above and below the ice sheet is 0 Celsius. Assuming that 70% of the radiation is absorbed at the surface of the ice, how long take to melt a layer of ice 1.2 cm thick?

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Your Solution:

The intensity of radiation is 600 watts / m^2.

If 70% of radiation is absorbed by the ice, then 0.70 * 600 watts / m^2 = 420 watts / m^2 per second which enters into the ice

Considering we take a piece of ice, which is 1 cm in length and 1 cm in width, then the height will be 1.2 cm. The total volume will be 1 * 1 * 1.2 cm^3 = 1.2 cm^3

The weight of 1.2 cm^3 of ice is 1.1 grams

@&

The acceptable way to find the mass is not to use a website that bypasses the reasoning process, but to use the density of ice. It's perfectly legitimate to look up the density of ice online, but not to use a calculator of that type.

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(According to this website: http://www.aqua-calc.com/calculate/volume-to-weight )

The heat of fusion of water is 333 J/g. To melt 1.1 grams of ice, we need 1.1 *333 = 366.3 J

The power P in watts (W) is equal to the energy E in joules (J), divided by the time period t in seconds (s):

Watts = Joule / second

420 watts = 366.3 J / x seconds

x seconds = 366.3 J / 420 watts

@&

420 watts falls on a square meter, not on a square centimeter.

*@

x = 0.87 seconds to melt a 1 cm by 1 cm by 1.2 cm ice cube

confidence rating #$&*: 3

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Given Solution:

** Thermal energy is not radiating in significant quantities from the ice, so only the incoming radiation needs to be considered, and as stated only 70% of that energy is absorbed by the ice..

· 70% of the incoming 600 watts/m^2 is 420 watts / m^2, or 420 Joules/second for every square meter if ice.

· Melting takes place at 0 C so there is no thermal exchange with the environment. Thus each square meter absorbs 420 Joules of energy per second.

We need to consider the volume of ice corresponding to a square meter. Having found that we can determine the energy required to melt the given thickness:

· A 1.2 cm thickness of ice will have a volume of .012 m^3 for every square meter of surface area; the mass will be close to 1000 kg/m^3, so there are about 12 kg of ice for every m^2 of surface (you can obtain a more accurate result by using the a more accurate density; the density of ice (which floats in water) is actually somewhat less than that of water).

· It takes about 330,000 Joules to melt a kg of ice at 0 C, so to melt 12 kg requires around 4,000,000 J. At 420 Joules/sec this will require roughly 10,000 seconds, or around 3 hours.

All these calculations were done mentally and are therefore approximate. You should check them yourself, using appropriately precise values of the constants, etc. **

Self-critique:

Your layer of ice is 1 meter by 1 meter by 1.2 cm. My layer of ice is 1 cm by 1 cm by 1.2 cm. For this reason, our answers are different, but I think a similar logic was used. I think the problem arises within the question, that the problem did not state the length and width of the ice cube.

@&

You can use any length and width dimensions you wish. The result will be the same regardless.

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Self-Critique Rating: 3

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Question: `q004. A body with a 1/2 m^2 surface area, at temperature 25 Celsius, has an emissivity of approximately 1. It exchanges energy by radiation with a large surface at temperature -20 Celsius. At what net rate does it lose energy?

By what percent would the rate of energy loss change if the large surface was at temperature -270 Celsius?

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Your Solution:

a)

Q = Area * Emissivity * Stefan Boltzmann constant * Time^4

Temperature conversion:

25 C + 273 = 298 Kelvin

-20C + 273 = 253 Kelvin

Q = 1/2 m^2 * 1 * 5.6703 * 10^-8 W/m^2*K^4 * ((298 K)^4 - (253 K)^4) = 107.42 W

b)

If temperature was -270 celsius, then

-270 C + 273 = 3 Kelvin

Q = 1/2 m^2 * 1 * 5.6703 * 10^-8 W/m^2*K^4 * ((298 K)^4 - (3 K)^4) = 223.58 W

Percent change:

(223.58 W - 107.42 / 107.42 W) x 100 = 108.14 %

So it increased by 108.14 %

confidence rating #$&*:

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Self-Critique Rating: 3

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Self-critique (if necessary):

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Self-critique rating:

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Self-critique (if necessary):

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Self-critique rating:

#*&!

@&

Not bad, but you have relied on online calculators rather than physics for some of your results.

You've also made a few errors. I think you'll understand when you read my notes, but if not feel free to ask.

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